Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2

被引:10047
作者
Naguib, Michael [1 ,2 ]
Kurtoglu, Murat [1 ,2 ]
Presser, Volker [1 ,2 ]
Lu, Jun [3 ]
Niu, Junjie [1 ,2 ]
Heon, Min [1 ,2 ]
Hultman, Lars [3 ]
Gogotsi, Yury [1 ,2 ]
Barsoum, Michel W. [1 ]
机构
[1] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA
[2] Drexel Univ, AJ Drexel Nanotechnol Inst, Philadelphia, PA 19104 USA
[3] Linkoping Univ, Dept Phys, IFM, S-58183 Linkoping, Sweden
基金
美国国家科学基金会; 欧洲研究理事会;
关键词
CARBIDE-DERIVED CARBON; SINGLE-LAYER MOS2; TI3SIC2; INTERCALATION; NANOSCROLLS; TRANSISTORS; NANOSHEETS; DIFFUSION; TI2INC; TI2ALC;
D O I
10.1002/adma.201102306
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
2D Ti 3C 2 nanosheets, multilayer structures, and conical scrolls produced by room temperature exfoliation of Ti 3AlC 2 in HF are reported. Since Ti 3AlC 2 is a member of a 60+ group of layered ternary carbides and nitrides, this discovery opens a door to the synthesis of a large number of other 2D crystals. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4248 / 4253
页数:6
相关论文
共 33 条
[1]  
Barsoum M.W., 2004, Encyclopedia of Materials: Science and Technology, P1
[2]  
Barsoum M.W., 2010, CERAMICS SCI TECHNOL, V2
[3]   The topotactic transformation of Ti3SiC2 into a partially ordered cubic Ti(C0.67Si0.06) phase by the diffusion of Si into molten cryolite [J].
Barsoum, MW ;
El-Raghy, T ;
Farber, L ;
Amer, M ;
Christini, R ;
Adams, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (10) :3919-3923
[4]   Processing and characterization of Ti2AlC, Ti2AlN, and Ti2AlC0.5N0.5 [J].
Barsoum, MW ;
Ali, M ;
El-Raghy, T .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2000, 31 (07) :1857-1865
[5]   The MN+1AXN phases:: A new class of solids;: Thermodynamically stable nanolaminates [J].
Barsoum, MW .
PROGRESS IN SOLID STATE CHEMISTRY, 2000, 28 (1-4) :201-281
[6]   Fabrication and electrical and thermal properties of Ti2InC, Hf2InC and (Ti,Hf)2InC [J].
Barsoum, MW ;
Golczewski, J ;
Seifert, HJ ;
Aldinger, F .
JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 340 (1-2) :173-179
[7]  
Brezesinski T, 2010, NAT MATER, V9, P146, DOI [10.1038/NMAT2612, 10.1038/nmat2612]
[8]   Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].
Coleman, Jonathan N. ;
Lotya, Mustafa ;
O'Neill, Arlene ;
Bergin, Shane D. ;
King, Paul J. ;
Khan, Umar ;
Young, Karen ;
Gaucher, Alexandre ;
De, Sukanta ;
Smith, Ronan J. ;
Shvets, Igor V. ;
Arora, Sunil K. ;
Stanton, George ;
Kim, Hye-Young ;
Lee, Kangho ;
Kim, Gyu Tae ;
Duesberg, Georg S. ;
Hallam, Toby ;
Boland, John J. ;
Wang, Jing Jing ;
Donegan, John F. ;
Grunlan, Jaime C. ;
Moriarty, Gregory ;
Shmeliov, Aleksey ;
Nicholls, Rebecca J. ;
Perkins, James M. ;
Grieveson, Eleanor M. ;
Theuwissen, Koenraad ;
McComb, David W. ;
Nellist, Peter D. ;
Nicolosi, Valeria .
SCIENCE, 2011, 331 (6017) :568-571
[9]  
Cullity B. D., 1978, ELEMENTS XRAY DIFFRA
[10]   Diffusion kinetics of the carburization and silicidation of Ti3SiC2 [J].
El-Raghy, T ;
Barsoum, MW .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (01) :112-119