Synthesis and structures of half-sandwich W(VI) tri(selenido) and W(II) selenolato complexes

被引：11

作者：

Kawaguchi, H

Tatsumi, K

机构：

[1] Nagoya Univ, Math Sci Res Ctr, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448595, Japan

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 14期

关键词：

D O I：

10.1039/b003303k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Cp*WCl4 with LiSeBut in THF in the presence of (BuNC)-N-t gave rise to Cp*W(SeBut)(CNBut)(3) 3, while treatment of the Cp*WCl4/LiSeBut reaction mixture with Li2Se2 followed by cation exchange with PPh4Br in MeCN afforded (PPh4)[Cp*WSe3] 1.

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页码：1299 / 1300

页数：2

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