Oligomeric flavanoids.: Part 34:: Doubly-linked proteracacinidin analogues from Acacia caffra and Acacia galpinii

被引:9
作者
Bennie, L
Coetzee, J
Malan, E
Woolfrey, JR
Ferreira, D [1 ]
机构
[1] Univ Mississippi, Sch Pharm, Pharmaceut Sci Res Inst, Natl Ctr Nat Prod Res, University, MS 38677 USA
[2] Univ Orange Free State, Dept Chem, ZA-9300 Bloemfontein, South Africa
[3] Univ Mississippi, Sch Pharm, Pharmaceut Sci Res Inst, Dept Med Chem, University, MS 38677 USA
基金
美国农业部; 新加坡国家研究基金会;
关键词
proteracacinidin; Acacia caffra; Acacia galpinii;
D O I
10.1016/S0040-4020(00)01036-X
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The rare series of doubly-linked proteracacinidin-type oligoflavanoids is extended by identification of four new analogues, oritin-(4 alpha-->7, 5-->6)-epioritin-4 alpha -ol 3, oritin-(4 beta-->7, 5-->6)-epioritin-4 alpha -ol 5, epioritin-(4 beta-->7, 5-->6)-epioritin-4 alpha -ol 7 and epioritin-(4 beta-->7, 5-->6)-oritin-4 alpha -ol 9. The same sources also afforded epioritin-(4P-->5, 3-->4)-oritin-4 alpha -ol 11 possessing a rare (4 beta-->5)- as well as a unique (3-->4)- ether linkage. Their structures and absolute configurations were established via spectroscopic methods. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:661 / 667
页数:7
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