1,2-additions of phenylselenenyl halides to phosphaalkynes

被引：3

作者：

Francis, MD

Jones, C

Junk, PC

Roberts, JL

机构：

[1] Univ Coll Swansea, Dept Chem, Swansea SA2 8PP, W Glam, Wales

[2] James Cook Univ N Queensland, Dept Chem & Chem Engn, Townsville, Qld 4811, Australia

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1997年 / 130卷

关键词：

phosphaalkyne; phenylselenenyl halide; selenophosphirenylium cation; selenophosphaalkene; crystal structure;

D O I：

10.1080/10426509708033693

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of a variety of selenophosphaalkenes by addition of phenylseleneyl halides to phosphaalkynes is described. The process is stereoselective and largely regioselective. The stereoselectivity is explained by postulating the presence of a cyclic selenophosphirenylium cation. The reaction of one of the prepared selenophosphaalkenes with (BuLi)-Bu-t is discussed.

引用

页码：23 / 34

页数：12

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