Cation migration and coercivity in mixed copper-cobalt spinel ferrite powders

被引：96

作者：

Tailhades, P

Villette, C

Rousset, A

Kulkarni, GU

Kannan, KR

Rao, CNR

Lenglet, M

机构：

[1] Univ Toulouse 3, Lab Chim Mat Inorgan, F-31062 Toulouse 4, France

[2] Jawaharlal Nehru Ctr Adv Sci Res, Chem & Phys Mat Unit, Bangalore 560064, Karnataka, India

[3] Univ Rouen, IUT, Lab Anal Spect & Traitement Surface Mat, F-76821 Mt St Aignan, France

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1998年 / 141卷 / 01期

关键词：

D O I：

10.1006/jssc.1998.7914

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mixed cobalt-copper spinel ferrites CoxCu1-xFe2O4 with acicular shape, prepared from oxalate precursors at moderate temperatures, have been investigated by several techniques to relate the coercivity With structure. The cation distribution in these ferrites is sensitive to the thermal history of the samples. Cation migration occurs during annealing in the 200-600 degrees C range in samples quenched from 710 degrees C and in the 350-600 degrees C range in slowly cooled samples. Because of shape anisotropy, tetragonal distortion, and directional order, coercivities from about 1500 to 4000 Oe are obtained in these ferrites. (C) 1998 Academic Press.

引用

页码：56 / 63

页数：8

共 30 条

[1] MAGNETO-OPTIC KERR EFFECT IN COFE2-XMXO4(M=MN,CR,AL) AND BAFE12-2X-COXTIXO19 WITH TETRAHEDRALLY COORDINATED CO2+ [J].