Coupling model explanation of salient dynamic properties of glass-forming substances

被引:55
作者
Ngai, KL [1 ]
机构
[1] USN, Res Lab, Washington, DC 20375 USA
关键词
D O I
10.1109/94.933340
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Most of the important and general dynamic properties of structural glass-forming substances have been classified into twelve different categories in a recent review. Within the same property in each category, by examining a large number of glass-formers, a pattern of variation is found which correlates with the departure of the structural relaxation of the glass-former from exponential decay or the quantity 1 - beta, where beta is the fractional exponent in the Kohlrausch expression exp[-(t/tau)(beta)], that well describes the time dependence of the structural a relaxation. The correlation of the patterns or trends with 1 - beta suggests that the salient dynamic properties, or phenomenology, of glass-forming substances, all are governed by the non-exponential nature of the structural relaxation, i.e, the quantity 1 - beta. Therefore, a theory or model capable of relating the structural relaxation time tau to 1 - beta has the potential of explaining most, if not all, of the salient dynamic properties of glass-forming substances. The coupling model of the author has this relation. In this accompanying paper we show the coupling model can either explain or interpret all these properties.
引用
收藏
页码:329 / 344
页数:16
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