Nanostructured metastable cermets of Ti-Al2O3 through activated SHS reaction

被引:38
作者
Mas-Guindal, M. J. [1 ]
Benko, E. [2 ]
Rodriguez, M. A. [1 ]
机构
[1] CSIC, Inst Ceram & Vidrio, Madrid 28049, Spain
[2] IOS, PL-30011 Krakow, Poland
关键词
composite materials; self-propagating high-temperature synthesis; X-ray diffraction;
D O I
10.1016/j.jallcom.2006.12.105
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cermets of Ti-Al2O3 are materials with promising applications in diverse fields like aeronautical or automobile industries. Recently, combustion synthesis (CS) has been used for its synthesis with very good results. In this paper, it is reported the use of self-propagating high-temperature synthesis (SHS) to obtain a metastable nanocrystalline cermet of alumina and titanium. As combustion synthesis is not self-sustaining, activation of the process has been made, either by applying field activation combustion synthesis (FACS) or by chemical activation, depending upon the conductivity of the sample. Quenching of reaction has allowed obtaining a metastable product with the configuration of high-temperature. Obtained materials have been characterised by SEM and XRD. Rietveld quantitative phase analysis and crystallite size calculations have been performed. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:352 / 358
页数:7
相关论文
共 31 条
[1]  
Bowen CR, 1997, BRIT CERAM T, V96, P25
[2]   Synchrotron diffraction studies of TiC/FeTi cermets obtained by SHS [J].
Contreras, L ;
Turrillas, X ;
Mas-Guindal, MJ ;
Vaughan, GBM ;
Kvick, Å ;
Rodríguez, MA .
JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (05) :1595-1600
[3]   Time-resolved XRD study of TiC-TiB2 composites obtained by SHS [J].
Contreras, L ;
Turrillas, X ;
Vaughan, GBM ;
Kvick, Å ;
Rodríguez, MA .
ACTA MATERIALIA, 2004, 52 (16) :4783-4790
[4]   TiC-NiAl composites obtained by SHS:: a time-resolved XRD study [J].
Curfs, C ;
Cano, IG ;
Vaughan, GBM ;
Turrillas, X ;
Kvick, Å ;
Rodríguez, MA .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2002, 22 (07) :1039-1044
[5]   Kinetic evaluation of combustion synthesis 3TiO2+7Al → 3TiAl+2Al2O3 using non-isothermal DSC method [J].
Fan, RH ;
Liu, B ;
Zhang, JD ;
Bi, JQ ;
Yin, YS .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 91 (01) :140-145
[6]   Modeling solution for electric field-activated combustion synthesis [J].
Feng, A ;
Graeve, OA ;
Munir, ZA .
COMPUTATIONAL MATERIALS SCIENCE, 1998, 12 (02) :137-155
[7]   Synthesis of NiO-YSZ composite particles for an electrode of solid oxide fuel cells by spray pyrolysis [J].
Fukui, T ;
Ohara, S ;
Naito, M ;
Nogi, K .
POWDER TECHNOLOGY, 2003, 132 (01) :52-56
[8]  
GLAZOVA VV, 1975, PHASE DIAGRAMS CERAM
[9]  
Günther R, 2001, J AM CERAM SOC, V84, P1509, DOI 10.1111/j.1151-2916.2001.tb00869.x
[10]   In situ processing of dense Al2O3-Ti aluminide interpenetrating phase composites [J].
Horvitz, D ;
Gotman, I ;
Gutmanas, EY ;
Claussen, N .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2002, 22 (06) :947-954