Neutral isonitrile adducts of alkali and alkaline earth metals

被引:30
作者
Caro, CF [1 ]
Hitchcock, PB [1 ]
Lappert, MF [1 ]
Layh, M [1 ]
机构
[1] Univ Sussex, Chem Lab, Brighton BN1 9QJ, E Sussex, England
关键词
D O I
10.1039/a708976g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Isonitriles are shown to form stable neutral adducts with some group 1 and 2 metal complexes; the synthesis and structures of [Li(N(R)C(Ph)NC (Ph)=CR2)(CNPh)](2), [LiNR2(CNPh)](2), [Mg(CHR2)(2)(CNC6H3Me2-2,6)(2)] and [Mg(CHR2)(mu-Br)(CNBut)](2) are described(R = SiMe3).
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页码:1297 / 1298
页数:2
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