New monodentate chiral phosphite ligands for asymmetric hydrogenation

被引：45

作者：

Hannen, P

Militzer, HC

Vogl, EM

Rampf, FA ^{[1
]}

机构：

[1] Bayer AG, Bayer Chem, D-51368 Leverkusen, Germany

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 17期

关键词：

D O I：

10.1039/b306793a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the synthesis of new chiral monodentate phosphite ligands with a biphenyl backbone, the axial chirality of which is introduced early in the synthesis and locked by a chiral alkylenedioxy bridge. We also describe results obtained with these ligands in rhodium-catalysed asymmetric hydrogenation of various substrates.

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收藏

页码：2210 / 2211

页数：2

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