Prebiotic carbohydrate synthesis:: zinc-proline catalyzes direct aqueous aldol reactions of α-hydroxy aldehydes and ketones

被引：102

作者：

Kofoed, J ^{[1
]}

Reymond, JL ^{[1
]}

Darbre, T ^{[1
]}

机构：

[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2005年 / 3卷 / 10期

关键词：

D O I：

10.1039/b501512j

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Zn-proline catalyzed aldolisation of glycoladehyde gave mainly tetroses whereas in the cross-aldolisation of glycoladehyde and rac-glyceraldehyde, pentoses accounted for 60% of the sugars formed with 20% of ribose.

引用

页码：1850 / 1855

页数：6

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