Design of potentially photorefractive liquid crystalline materials: Derivatives of 3,6-disubstituted carbazole

被引:34
作者
Belloni, M [1 ]
Kariuki, BM [1 ]
Manickam, M [1 ]
Wilkie, J [1 ]
Preece, JA [1 ]
机构
[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England
关键词
D O I
10.1021/cg049580s
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The incorporation of photorefractive molecular units, such as carbazole, into anisotropic materials (liquid crystals) may offer many advantages over conventional electrical poling of photorefractive polymers. Thus, a series of symmetric 3,6-disubstituted carbazole derivatives with a bent molecular shape have been synthesized and characterized. The influence of the nature of the symmetric substituents on the carbazole is investigated through comparison of crystal packing and electrostatic potentials.
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收藏
页码:1443 / 1450
页数:8
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