Novel synthesis of diazetidine-2,4-dione by ring expansion of diaziridinone

被引：17

作者：

Komatsu, M

Tamabuchi, S

Minakata, S

Ohshiro, Y

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 5650871, Japan

[2] Kinki Univ, Sci & Technol Res Inst, Osaka 5770818, Japan

来源：

HETEROCYCLES | 1999年 / 50卷 / 01期

关键词：

D O I：

10.3987/COM-98-S(H)45

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of N,N'-di-tert-butyldiaziridinone with Ni(CO)(4) under an atmosphere of carbon monoxide caused a carbonylative ring expansion to give di-tert-butyldiazetidinedione in good yield. In the presence of diphenylketene under the conditions, azetidinedione derivative was obtained.

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页码：67 / 70

页数：4

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