Thiolation of iodobenzene catalyzed by fluorinated bis-imino nickel NNN pincer complexes

被引：47

作者：

Baldovino-Pantaleón, O ^{[1
]}

Hernández-Ortega, S ^{[1
]}

Morales-Morales, D ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 10期

关键词：

thiolation; C-S coupling reactions; pincer complexes; nickel complexes; catalysis; crystal structures;

D O I：

10.1016/j.inoche.2005.07.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of bis-imino nickel(II) NNN pincer complexes of the type [NiCl2{C5H3N-2,6-(CHNArf)(2)}]; Ar-f = C6H3-2,3-F-2 (1), C6H3-2,5-F-2 (2), C6H3-3,4-F-2 (3), C6H3-3,5-F-2 (4), C6H2-2,3,4-F-3 (5), C6H2-2,3,6-F-3 (6), C6H2-2,4,5-F-3 (7), and C6H2-2,4,6-F-3 (8), has been achieved and its reactivity explored proving these compounds to be efficient in the alkyl and aryl thiolation of iodobenzene. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：955 / 959

页数：5

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