Studies of a high temperature proton exchange membrane based on incorporating an ionic liquid cation 1-butyl-3-methylimidazolium into a Nafion matrix

被引：91

作者：

Yang, Jingshuai ^{[1
]}

Che, Quantong ^{[1
]}

Zhou, Lu ^{[1
]}

He, Ronghuan ^{[1
]}

Savinell, Robert F. ^{[2
]}

机构：

[1] Northeastern Univ, Dept Chem, Coll Sci, Shenyang 110819, Peoples R China

[2] Case Western Reserve Univ, Dept Chem Engn, Cleveland, OH 44106 USA

来源：

ELECTROCHIMICA ACTA | 2011年 / 56卷 / 17期

关键词：

High temperature proton exchange membrane; Ionic liquid; Nafion; Proton conductivity; Methanol permeability; DOPED POLYBENZIMIDAZOLE MEMBRANES; POLYMER ELECTROLYTE MEMBRANES; CONDUCTING MEMBRANES; COMPOSITE MEMBRANES; METHANOL; OPERATION; HETEROPOLYACIDS; CHALLENGES;

D O I：

10.1016/j.electacta.2011.04.112

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

High temperature proton exchange membranes based on Nation were prepared by incorporating the polymer with ionic liquid cation 1-butyl-3-methylimidazolium (BMIm) and doping with phosphoric acid (PA). We found that using the hydroxide form rather than the chloride form of BMIm incorporated more readily the BMIm cation into Nafion film. A mole ratio of about 2 of BMIm cation to Nation repeat unit, i.e., lambda(BMIm/Nafion), was reached with the hydroxide form BMIm. The incorporated BMIm cation enhanced the doping of phosphoric acid into Nation. A proton conductivity of 10.9 mS cm(-1) and a tensile stress at break of 5.3 MPa were achieved, respectively, with a composite membrane of Nafion/2.3BMIm/5.2PA in molar ratio at 160 degrees C without humidification. (C) 2011 Elsevier Ltd. All rights reserved.

引用

页码：5940 / 5946

页数：7

共 47 条

[1] Investigation of a direct methanol fuel cell based on a composite Nafion®-silica electrolyte for high temperature operation [J].

Antonucci, PL ;

Aricò, AS ;

Cretì, P ;

Ramunni, E ;

Antonucci, V .

SOLID STATE IONICS, 1999, 125 (1-4) :431-437

[2]

Armand M, 2009, NAT MATER, V8, P621, DOI [10.1038/NMAT2448, 10.1038/nmat2448]

[3] Preparation and characterization of new anhydrous, conducting membranes based on composites of ionic liquid trifluoroacetic propylamine and polymers of sulfonated poly (ether ether) ketone or polyvinylidenefluoride [J].

Che, Quantong ;

Sun, Baoying ;

He, Ronghuan .

ELECTROCHIMICA ACTA, 2008, 53 (13) :4428-4434

[4] Phosphoric acid doped high temperature proton exchange membranes based on sulfonated polyetheretherketone incorporated with ionic liquids [J].

Che, Quantong ;

He, Ronghuan ;

Yang, Jingshuai ;

Feng, Li ;

Savinell, Robert F. .

ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (05) :647-649

[5] A Study on Proton Conductivity of Composite Membranes with Various Ionic Liquids for High-Temperature Anhydrous Fuel Cells [J].

Cho, EunKyung ;

Park, Jin-Soo ;

Sekhon, S. S. ;

Park, Gu-Gon ;

Yang, Tae-Hyun ;

Lee, Won-Yong ;

Kim, Chang-Soo ;

Park, Seung-Bin .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2009, 156 (02) :B197-B202

[6] Nafion® 115/zirconium phosphate composite membranes for operation of PEMFCs above 100 °C [J].

Costamagna, P ;

Yang, C ;

Bocarsly, AB ;

Srinivasan, S .

ELECTROCHIMICA ACTA, 2002, 47 (07) :1023-1033

[7] Chitosan/heteropolyacid composite membranes for direct methanol fuel cell [J].

Cui, Zhiming ;

Xing, Wei ;

Liu, Changpeng ;

Liao, Jianhui ;

Zhang, Hong .

JOURNAL OF POWER SOURCES, 2009, 188 (01) :24-29

[8]

Cull SG, 2000, BIOTECHNOL BIOENG, V69, P227

[9] Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].

Decher, G .

SCIENCE, 1997, 277 (5330) :1232-1237

[10] Structure-Relaxation Interplay of a New Nanostructured Membrane Based on Tetraethylammonium Trifluoromethanesulfonate Ionic Liquid and Neutralized Nafion 117 for High-Temperature Fuel Cells [J].

Di Noto, Vito ;

Negro, Enrico ;

Sanchez, Jean-Yves ;

Iojoiu, Christina .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (07) :2183-2195

← 1 2 3 4 5 →