Self-assembly of zinc aminoporphyrins

被引：81

作者：

Gardner, M

Guerin, AJ

Hunter, CA ^{[1
]}

Michelsen, U

Rotger, C

机构：

[1] Univ Sheffield, Dept Chem, Krebs Inst Biomolec Res, Sheffield S3 7HF, S Yorkshire, England

[2] Pfizer Ltd, Sandwich CT13 9NJ, Kent, England

来源：

NEW JOURNAL OF CHEMISTRY | 1999年 / 23卷 / 03期

关键词：

D O I：

10.1039/a807876i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aniline-zinc porphyrin interaction is an order of magnitude weaker than the corresponding pyridine-zinc porphyrin interaction, but it is still strong enough to cause self-assembly of zinc aminoporphyrins in solution. Three isomeric systems are reported, two form self-assembled dimers, but the geometry of the third forces it to form an open chain oligomer. The stabilities and structures of the complexes have been determined using H-1 NMR spectroscopy.

引用

页码：309 / 316

页数：8

共 28 条

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