Synthesis, structure, and [60]fullerene complexation properties of azacalix[m]arene[n]pyridines

被引：254

作者：

Wang, MX ^{[1
]}

Zhang, XH ^{[1
]}

Zheng, QY ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Biol Chem Lab, Beijing 100080, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 07期

关键词：

calixarenes; fullerenes; host-guest systems; supramolecular chemistry;

D O I：

10.1002/anie.200351975

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Remarkably stable C60 and C70 complexes with stability constants Ks of 70 680 ± 2060 and 136 620 ± 3770 M-1, respectively, are formed by azacalix[4]arene[4]pyridine 1. The smaller-ring-homologue azacalix[2]arene[2]pyridine and compound 1 were readily synthesized, and they adopt a heavily twisted 1,3-alternate and a 1,2,3-partial cone conformation, respectively, in the solid state (see picture).

引用

页码：838 / 842

页数：5

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