Noble gases and microporous frameworks; from interaction to application

被引：68

作者：

Dorcheh, A. Soleimani ^{[1
,3
]}

Denysenko, D. ^{[2
]}

Volkmer, D. ^{[2
]}

Donner, W. ^{[3
]}

Hirscher, M. ^{[1
]}

机构：

[1] Max Planck Inst Intelligente Syst, D-70569 Stuttgart, Germany

[2] Univ Augsburg, Inst Phys, D-86135 Augsburg, Germany

[3] Tech Univ Darmstadt, Dept Mat Sci, D-64287 Darmstadt, Germany

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2012年 / 162卷

关键词：

Microporous frameworks; Noble gas separation; Thermal desoprtion spectroscopy; METAL-ORGANIC FRAMEWORKS; ADSORPTION; DESORPTION; HYDROGEN; XENON; HEATS;

D O I：

10.1016/j.micromeso.2012.06.004

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The noble gas storage and separation capability of three classes of microporous frameworks (MFs) including Metal-Organic Frameworks (HKUST-1 and MFU-4l), Covalent-Organic Frameworks (COF-102) and Zeolite Imidazolate Frameworks (ZIF-8) were studied using thermal desorption spectroscopy (TDS). The maxima in the TDS spectra were correlated to the adsorption sites and strength of interactions. The difference in the final desorption temperature for xenon and krypton was correlated to the separation capability of the frameworks. The results show that MFU-4l and HKUST-1 are potential candidates for separation and storage of krypton and xenon. Further sorption studies have proved the ability of both candidates in Kr/Xe separation in larger scale. (C) 2012 Elsevier Inc. All rights reserved.

引用

页码：64 / 68

页数：5

共 25 条

[1]

[Anonymous], ZIF 8 BAS Z1200 GAS

[2] Kinetic separation of carbon dioxide and methane on a copper metal-organic framework [J].

Bao, Zongbi ;

Alnemrat, Sufian ;

Yu, Liang ;

Vasiliev, Igor ;

Ren, Qilong ;

Lu, Xiuyang ;

Deng, Shuguang .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 357 (02) :504-509

[3] THE HEATS OF ADSORPTION OF THE INERT GASES ON CHARCOAL AT LOW PRESSURE [J].

CHACKETT, KF ;

TUCK, DG .

TRANSACTIONS OF THE FARADAY SOCIETY, 1957, 53 (12) :1652-1658

[4] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[5] Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes [J].

Denysenko, Dmytro ;

Grzywa, Maciej ;

Tonigold, Markus ;

Streppel, Barbara ;

Krkljus, Ivana ;

Hirscher, Michael ;

Mugnaioli, Enrico ;

Kolb, Ute ;

Hanss, Jan ;

Volkmer, Dirk .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (06) :1837-1848

[6] TEMPERATURE-PROGRAMMED DESORPTION AND REACTION - APPLICATIONS TO SUPPORTED CATALYSTS [J].

FALCONER, JL ;

SCHWARZ, JA .

CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1983, 25 (02) :141-227

[7] Heats of Adsorption for Seven Gases in Three Metal-Organic Frameworks: Systematic Comparison of Experiment and Simulation [J].

Farrusseng, David ;

Daniel, Cecile ;

Gaudillere, Cyril ;

Ravon, Ugon ;

Schuurman, Yves ;

Mirodatos, Claude ;

Dubbeldam, David ;

Frost, Houston ;

Snurr, Randall Q. .

LANGMUIR, 2009, 25 (13) :7383-7388

[8] Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications [J].

Furukawa, Hiroyasu ;

Yaghi, Omar M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (25) :8875-8883

[9]

Haussinger P., 2000, ULLMANNS ENCY IND CH

[10]

Herm Z, 2011, ABSTR PAP AM CHEM S, V241

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