Determination of rare earth impurities in high purity zirconium dioxide by electrothermal vaporization inductively coupled plasma atomic emission spectrometry using 1-phenyl-3-methyl-4-benzoyl-5-pyrazone as extractant and chemical modifier

被引：25

作者：

Chen, SZ ^{[1
]}

Peng, TY ^{[1
]}

Jiang, ZC ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China

来源：

ANALYTICAL LETTERS | 1999年 / 32卷 / 02期

基金：

美国国家科学基金会;

关键词：

electrothermal vaporization; inductively coupled plasma atomic emission spectrometry; high purity zirconium dioxide; rare earth element; rare earth-PMBP chelate;

D O I：

10.1080/00032719908542829

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel method has been developed for the determination of trace La, Eu and Y in high purity ZrO2 by electrothermal vaporization inductively coupled plasma atomic emission spectrometry (ETV-ICP-AES) with 1-phenyl-3-methyl-4-benzoyl-5-pyrazone (PMBP) as extractant and chemical modifier. The matrix was quantitatively separated from the selected elements in 6M HNO3 medium by extraction with 0.1M PMBP in chloroform. The vaporization behaviors, effect factors and analytical characteristics of above selected elements were investigated in detail. Under the optimized conditions, the detection limits were 8.0, 0.9 and 1.0ng ml(-1) for La, Eu and Y with the relative standard deviations of 3.3, 3.4 and 4.0% (n=7, c=0.5 mu g ml(-1)), respectively. The proposed method has been applied to determine trace impurities in ZrO2.

引用

页码：411 / 421

页数：11

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