catena-Poly[[[tetrakis(dimethylformamide-κO)-magnesium(II)]-μ-diphenylphosphato-κ2O:O′]trifluoromethanesulfonate]

被引：5

作者：

Adams, H ^{[1
]}

Rolfe, A ^{[1
]}

Jones, S ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2005年 / 61卷

关键词：

D O I：

10.1107/S1600536805016880

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Mg(C12H10O4P)(C3H7NO)(4)](CF3O3S), consists of diphenylphosphate anions linked into infinite chains by bridging magnesium ions, which are also coordinated by dimethylformamide molecules. A non-coordinated trifluoromethanesulfonate counter-ion provides charge balance. Both crystallographically distinct magnesium cations occupy special positions with (1) over bar site symmetry.

引用

页码：M1251 / M1252

页数：2

共 6 条

[1]

*BRUK AXS INC, 1997, SMART SAINT SADABS S

[2]

CREMLYN RJW, 1958, J CHEM SOC, P528

[3] CRYSTAL-STRUCTURE OF MAGNESIUM DIETHYL PHOSPHATE, MG[PO2(OC2H5)2]2 [J].

EZRA, FS ;

COLLIN, RL .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1973, 29 (JUL15) :1398-1403

[4] CRYSTAL AND MOLECULAR-STRUCTURE OF PENTAAQUOHEXA(DIPHENYL PHOSPHATO)TRIMAGNESIUM(II), [(C6H5O)2P(O)O]6MG3(H2O)5, A HYDRATED MAGNESIUM PHOSPHODIESTER SALT WITH PENTACOORDINATE AND HEXACOORDINATE METAL-IONS [J].

NARAYANAN, P ;

RAMIREZ, F ;

MCCAFFREY, T ;

CHAW, YF ;

MARECEK, JF .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (01) :24-31

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF TETRAPHYRIDINE-BIS(DIETHYLPHOHOROTHIOATO) MAGNESIUM(II), A MODEL SUBSTANCE FOR POLYNUCLEOTIDE PHOSPHOROTHIOATES [J].

SCHWALBE, CH ;

GOODY, R ;

SAENGER, W .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, 29 (OCT15) :2264-2272

[6]

Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR

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