The mechanism of the double bond cleavage in the titanium zeolite-catalyzed oxidation of alpha-methylstyrene by hydrogen peroxide: The beta-hydroperoxy alcohol as intermediate

被引：12

作者：

Adam, W ^{[1
]}

Corma, A ^{[1
]}

Martinez, A ^{[1
]}

Renz, M ^{[1
]}

机构：

[1] UNIV POLITECN VALENCIA, CSIC, INST TECNOL QUIM, E-46022 VALENCIA, SPAIN

来源：

CHEMISCHE BERICHTE-RECUEIL | 1996年 / 129卷 / 12期

关键词：

zeolites; titanium; epoxidation; double bond cleavage;

D O I：

10.1002/cber.19961291209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is unequivocally shown that acetophenone, an oxidation product in the titanium zeolite-catalyzed oxidation of alpha-methylstyrene, derives from 2-hydroperoxy-2-phenyl-1-propanol as intermediate, which was detected and isolated in this reaction for the first time.

引用

页码：1453 / 1455

页数：3

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