Synthesis of soluble donor-acceptor double-cable polymers based on polythiophene and tetracyanoanthraquinodimethane (TCAQ)

被引:36
作者
Giacalone, F [1 ]
Segura, JL
Martín, N
Catellani, M
Luzzati, S
Lupsac, N
机构
[1] Univ Complutense, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain
[2] CNR, Ist Studio Macromol, I-20133 Milan, Italy
关键词
D O I
10.1021/ol034324e
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Novel suitably functionalized tetracyanoanthraquinodimethane (TCAQ) derivatives covalently linked to thiophene moieties have been synthesized. The thiophene-based monomers have been chemically polymerized and copolymerized to yield new and soluble donor-acceptor double-cable polymers. The absorption and emission data reveal that the optical properties can be finely tuned by modifying the ratio of monomers in the copolymerization process.
引用
收藏
页码:1669 / 1672
页数:4
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