Highly efficient dehydrogenation of indolines to indoles using hydroxyapatite-bound Pd catalyst

被引:113
作者
Hara, T [1 ]
Mori, K [1 ]
Mizugaki, T [1 ]
Ebitani, K [1 ]
Kaneda, K [1 ]
机构
[1] Osaka Univ, Grad Sch Engn Sci, Dept Sci & Chem Engn, Osaka 5608531, Japan
基金
日本学术振兴会;
关键词
dehydrogenation; indoline; indole; heterogeneous Pd catalyst; hydroxyapatite;
D O I
10.1016/S0040-4039(03)01550-8
中图分类号
O62 [有机化学];
学科分类号
070303 [有机化学]; 081704 [应用化学];
摘要
A hydroxyapatite-bound palladium catalyst was found to be effective for the dehydrogenation of various types of indolines to give the corresponding indoles. Moreover, the catalyst was readily recovered from the reaction mixture, and could be reused without any loss of its catalytic activity. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码:6207 / 6210
页数:4
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