Concave polyarenes with sulfide-linked flaps and tentacles: new electron-rich hosts for fullerenes

被引:96
作者
Georghiou, PE [1 ]
Tran, AH
Mizyed, S
Bancu, M
Scott, LT
机构
[1] Mem Univ Newfoundland, Dept Chem, St John, NF A1B 3X7, Canada
[2] Yarmouk Univ, Dept Chem, Irbid, Jordan
[3] Boston Coll, Merket Chem Ctr, Dept Chem, Chestnut Hill, MA 02467 USA
基金
巴西圣保罗研究基金会;
关键词
D O I
10.1021/jo0503761
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Pentakis(1,4-benzodithiino)corannulene (6) in CS2 formed the strongest 1:1 complexes with C-60 and C-70 of any corannulene derivative yet reported. The 1,3,5,7,9-pentakis(propylthio)corannulene (4b) formed weaker 1:1 complexes with C-60 and C-70 in CS2, whereas the decakis(propylthio)corannulene (5b) and unsubstituted corannulene (1) showed no evidence for complexation with either C-60 or C-70 in CS2.
引用
收藏
页码:6158 / 6163
页数:6
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