A polyoxometalate-based manganese carboxylate cluster

被引:111
作者
Fang, Xikui [1 ]
Koegerler, Paul [1 ,2 ]
机构
[1] Iowa State Univ, Ames Lab, Ames, IA 50011 USA
[2] Rhein Westfal TH Aachen, Inst Inorgan Chem, D-52074 Aachen, Germany
关键词
D O I
10.1039/b804111c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The functionalization of a pre-formed, high oxidation state {(CeMn6IV)-Mn-IV} cluster with a lacunary phosphotungstate, [alpha-P2W15O56](12-), exemplifies a straightforward route for grafting redox-active building blocks to existing Mn-carboxylate clusters and modeling their deposition onto metal oxide surfaces.
引用
收藏
页码:3396 / 3398
页数:3
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