Positive shifts of the C60 reduction potentials by introducing cyano groups

被引：9

作者：

Fan, LZ ^{[1
]}

Li, YF ^{[1
]}

Li, FY ^{[1
]}

Li, YL ^{[1
]}

Zhu, DB ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 294卷 / 4-5期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0009-2614(98)00867-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The electrochemical properties of a new C-60 derivative with a tetracyanotetrahydrofuran addend were investigated by cyclic voltammetry. Its reduction potentials were measured in several solution with different solvents. It was found that the first reduction of the derivative shifted positively by 170 mV compared with that of C-60, reflecting its stronger electron-accepting ability. The NIR characteristic absorption bands of its monoanion and dianion were also obtained. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：443 / 446

页数：4

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