K3B6O10Cl: A New Structure Analogous to Perovskite with a Large Second Harmonic Generation Response and Deep UV Absorption Edge

被引：645

作者：

Wu, Hongping ^{[1
,2
]}

Pan, Shilie ^{[1
]}

Poeppelmeier, Kenneth R. ^{[3
]}

Li, Hongyi ^{[1
]}

Jia, Dianzeng ^{[2
]}

Chen, Zhaohui ^{[1
]}

Fan, Xiaoyun ^{[1
]}

Yang, Yun ^{[1
]}

Rondinelli, James M. ^{[4
]}

Luo, Haosu ^{[5
]}

机构：

[1] Chinese Acad Sci, Xinjiang Key Lab Elect Informat Mat & Devices, Xinjiang Tech Inst Phys & Chem, Urumqi 830011, Peoples R China

[2] Xinjiang Univ, Coll Chem & Chem Engn, Urumqi 830046, Peoples R China

[3] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[4] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA

[5] Chinese Acad Sci, State Key Lab High Performance Ceram & Superfine, Shanghai Inst Ceram, Shanghai 201800, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 20期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

NONLINEAR-OPTICAL CRYSTAL; AUGMENTED-WAVE METHOD; K2AL2B2O7; CRYSTALS; BORATE CRYSTALS; SINGLE-CRYSTALS; KBBF CRYSTAL; GROWTH; RB; POLAR; BI2ZNOB2O6;

D O I：

10.1021/ja111083x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Introduction of the Cl anion in the borate systems generates a new perovskite-like phase, K3B6O10Cl, which exhibits a large second harmonic response, about four times that of KH2PO4 (KDP), and is transparent from the deep UV (180 nm) to middle-IR region. K3B6O10Cl crystallizes in the noncentrosymmetric and rhombohedral space group R3m. The structure consists of the A-site hexaborate [B6O10] groups and the BX3 Cl-centered octahedral [ClK6] groups linked together through vertices to form the perovskite framework represented by ABX(3).

引用

页码：7786 / 7790

页数：5

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