Reductive alkylation of muorinated graphite

被引：29

作者：

Chakraborty, Soma

Guo, Wenhua

Hauge, Robert H.

Billups, W. E. ^{[1
]}

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

来源：

CHEMISTRY OF MATERIALS | 2008年 / 20卷 / 09期

关键词：

D O I：

10.1021/cm800060q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fluorinated graphite (CFx) was alkylated reductively to yield functionalized graphite platelets comprised of six to 23 graphene sheets. A free radical mechanism involving a single electron transfer was proposed. The higher level of functionalization that resulted from the fluorinated substrate led to materials that exhibited an enhanced solubility in organic solvents.

引用

页码：3134 / 3136

页数：3

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