Reactor design for in situ X-ray scattering studies of nanoparticle formation in supercritical water syntheses

被引：40

作者：

Breraholm, Martin ^{[1
,2
]}

Jensen, Henrik ^{[3
]}

Iversen, Steen Brummerstedt ^{[3
]}

Iversen, Bo Brummerstedt ^{[1
,2
]}

机构：

[1] Aarhus Univ, Dept Chem, DK-8000 Aarhus C, Denmark

[2] Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, DK-8000 Aarhus C, Denmark

[3] SCF Technol AS, DK-2730 Herlev, Denmark

来源：

JOURNAL OF SUPERCRITICAL FLUIDS | 2008年 / 44卷 / 03期

关键词：

Supercritical synthesis; nanoparticles; In situ X-ray scattering; reactor design;

D O I：

10.1016/j.supflu.2007.09.029

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In situ X-ray studies have been widely used in both solid-state chemistry and wet-chemistry to study a variety of reactions and processes, but so far studies of syntheses in the supercritical phase are few and mainly limited to static experiments. Here the design of reactor cells for time-resolved in situ X-ray studies of synthesis in supercritical water is discussed and examples of the information that can be obtained are given for both batch and continuous flow reactors. It is shown that highly useful information on process kinetics can be obtained despite the considerable experimental challenges. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：385 / 390

页数：6

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