Soft-x-ray spectroscopy measurements of the p-like density of states of B in MgB2 and evidence for surface boron oxides on exposed surfaces -: art. no. 132504

被引:44
作者
Callcott, TA [1 ]
Lin, L
Woods, GT
Zhang, GP
Thompson, JR
Paranthaman, M
Ederer, DL
机构
[1] Univ Tennessee, Dept Phys & Astron, Knoxville, TN 37996 USA
[2] Oak Ridge Natl Lab, Div Solid State, Oak Ridge, TN 37831 USA
[3] Oak Ridge Natl Lab, Div Chem & Analyt Sci, Oak Ridge, TN 37831 USA
[4] Tulane Univ, Dept Phys, New Orleans, LA 70118 USA
关键词
D O I
10.1103/PhysRevB.64.132504
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Soft-x-ray absorption and fluorescence measurements are reported for the K edge of B in MgB2. The measurements confirm a high density of B p(xy)(sigma) states at the Fermi edge and extending to approximately 0.9 eV above the edge. A strong resonance is observed in elastic scattering through a core exciton derived from out-of-plane p(z)(pi*) states. Another strong resonance, observed in both elastic and inelastic spectra, is identified as a product of surface boron oxides.
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页数:3
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