Exploitation of an unexpected in situ heteroaromatic bromination for the synthesis of a porphyrin functionalized nucleoside.

被引：21

作者：

Solladié, N

Gross, M

机构：

[1] Univ Strasbourg, Lab Electrochim & Chim Phys Corps Solide, F-67070 Strasbourg, France

[2] CNRS, F-67070 Strasbourg, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(99)00483-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 2'-deoxyuridine derivative functionalized via an acetylenic junction with a Zn(II) tetraarylporphyrin has been prepared. Is also reported an unexpected in situ bromination of the uracil nucleic base at the C5 position, which occurs during the transformation of a dibromo-olefin into its corresponding acetylenic anion. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

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页码：3359 / 3362

页数：4

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