Using polymers to control substrate, ligand, or catalyst solubility

被引：37

作者：

Bergbreiter, DE ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2001年 / 39卷 / 14期

关键词：

polymer-supported synthesis; solubility; lower critical-solution temperature; biphasic; catalysis;

D O I：

10.1002/pola.1212

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The attributes and design of soluble polymer supports for catalysis and synthesis are discussed. By manipulating polymer structure, polymer supports can be prepared so that the solubility of an attached reagent. substrate, or ligand is affected by heating, cooling, pH, or solvent identity. Supports with such engineered solubility are useful both in organic synthesis and catalysis. They can be used as purification handles in organic synthesis as a way to recover catalysts, as a way to turn reactions on or off. and more generally. as a handle for separations. (C) 2001 John Wiley & Sons. Inc.

引用

页码：2351 / 2363

页数：13

共 71 条

[1] Albericio F, 2000, SOLID-PHASE SYNTHESIS, P275
[2] [Anonymous], 1985, ANGEW CHEM
[3] Homogeneous catalysis - Toward greener chemistry
Baker, RT
Tumas, W
[J]. SCIENCE, 1999, 284 (5419) : 1477 - 1479
[4] Barthel-Rosa LP, 1999, COORDIN CHEM REV, V190, P587
[5] KINETIC STUDIES OF LIQUID-PHASE PEPTIDE-SYNTHESIS
BAYER, E
MUTTER, M
UHMANN, R
POLSTER, J
MAUSER, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (23) : 7333 - 7336
[6] POLYETHYLENE-BOUND RHODIUM(I) HYDROGENATION CATALYSTS
BERGBREITER, DE
CHANDRAN, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (01) : 174 - 179
[7] POLYETHYLENE CARBOXYLATE-BOUND TRIRUTHENIUM CLUSTERS AS ALCOHOL OXIDATION CATALYSTS
BERGBREITER, DE
TREADWELL, DR
[J]. REACTIVE POLYMERS, 1990, 12 (03): : 291 - 295
[8] Palladium-catalyzed C-C coupling under thermomorphic conditions
Bergbreiter, DE
Osburn, PL
Wilson, A
Sink, EM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (38) : 9058 - 9064
[9] Poly(N-isopropylacrylamide) soluble polymer supports in catalysis and synthesis
Bergbreiter, DE
Case, BL
Liu, YS
Caraway, JW
[J]. MACROMOLECULES, 1998, 31 (18) : 6053 - 6062
[10] ANIONIC SYNTHESES OF TERMINALLY FUNCTIONALIZED ETHYLENE OLIGOMERS
BERGBREITER, DE
BLANTON, JR
CHANDRAN, R
HEIN, MD
HUANG, KJ
TREADWELL, DR
WALKER, SA
[J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1989, 27 (12) : 4205 - 4226

← 1 2 3 4 5 6 7 8 →