Hydrogen-bond-induced clustering in the fragile glass-forming liquid m-toluidine:: Experiments and simulations

被引:80
作者
Morineau, D [1 ]
Alba-Simionesco, C [1 ]
机构
[1] Univ Paris Sud, CPMA, CNRS URA 1104, F-91405 Orsay, France
关键词
D O I
10.1063/1.477514
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We study the "prepeak" appearing in the static structure factor of the molecular glass-former m-toluidine by means of neutron scattering experiments and Monte Carlo simulations. The occurrence of this prepeak is interpreted as resulting from spatial organization of the molecules that goes beyond the usual short range liquid order and has a typical length scale of several molecular diameters. The origin of this phenomenon, as well as its specific temperature and density dependence, is explained by the competition between hydrogen-bonding interactions that tend to favor clustering and steric hindrance between aromatic rings that limits the extension of the H-bond network. Finally, effects of such clustering on the relaxational properties of the liquid and on the glass transition are discussed. (C) 1998 American Institute of Physics. [S0021-9606(98)51743-6].
引用
收藏
页码:8494 / 8503
页数:10
相关论文
共 37 条
  • [1] ON TEMPERATURE DEPENDENCE OF COOPERATIVE RELAXATION PROPERTIES IN GLASS-FORMING LIQUIDS
    ADAM, G
    GIBBS, JH
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 43 (01) : 139 - &
  • [2] ALBASIMIONESCO C, IN PRESS J CHEM PHYS
  • [3] NEUTRON-SCATTERING DETERMINATION OF LOCAL ORDER IN AMORPHOUS AND LIQUID-SYSTEMS USING A POSITION-SENSITIVE DETECTOR
    AMBROISE, JP
    BELLISSENTFUNEL, MC
    BELLISSENT, R
    [J]. REVUE DE PHYSIQUE APPLIQUEE, 1984, 19 (09): : 731 - 734
  • [4] ANGELL CA, 1990, RELAXATION COMPLEX S
  • [5] A NEUTRON AND X-RAY-DIFFRACTION STUDY OF THE BINARY-LIQUID AROMATIC SYSTEM BENZENE-HEXAFLUOROBENZENE .1. THE PURE COMPONENTS
    BARTSCH, E
    BERTAGNOLLI, H
    SCHULZ, G
    CHIEUX, P
    [J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1985, 89 (02): : 147 - 156
  • [6] A NEUTRON-SCATTERING STUDY OF LIQUID D2O UNDER PRESSURE AND AT VARIOUS TEMPERATURE
    BELLISSENTFUNEL, MC
    BOSIO, L
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (09) : 3727 - 3735
  • [7] THE INELASTICITY CORRECTION FOR LIQUID WATER IN NEUTRON-SCATTERING
    BELLISSENTFUNEL, MC
    BOSIO, L
    TEIXEIRA, J
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 1991, 3 (22) : 4065 - 4074
  • [8] MULTIPLE SCATTERING OF NEUTRONS IN VANADIUM AND COPPER
    BLECH, IA
    AVERBACH, BL
    [J]. PHYSICAL REVIEW, 1965, 137 (4A): : 1113 - &
  • [9] Dynamic heterogeneity in supercooled ortho-terphenyl studied by multidimensional deuteron NMR
    Bohmer, R
    Hinze, G
    Diezemann, G
    Geil, B
    Sillescu, H
    [J]. EUROPHYSICS LETTERS, 1996, 36 (01): : 55 - 60
  • [10] NONEXPONENTIAL RELAXATIONS IN STRONG AND FRAGILE GLASS FORMERS
    BOHMER, R
    NGAI, KL
    ANGELL, CA
    PLAZEK, DJ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (05) : 4201 - 4209