Cyanidation of halogen compounds and esters catalyzed by PEG400 without solvent

被引：12

作者：

Cao, YQ ^{[1
]}

Chen, BH ^{[1
]}

Pei, BG ^{[1
]}

机构：

[1] Hebei Univ, Dept Chem, Baoding 071002, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2001年 / 31卷 / 14期

关键词：

'Dry' [ - Aliphatic nitriles - Aromatic nitriles - Cyanidation - PEG-400 - Phase transfer catalysts - Solvent free conditions - Synthesised;

D O I：

10.1081/SCC-100104474

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Primary aliphatic and aromatic nitriles were synthesized in excellent yields (84-96%) and purity by the cyanidation of halogen compounds and esters with dry powdered sodium cyanide catalysed by phase transfer catalyst PEG400 under solvent-free conditions.

引用

页码：2203 / 2207

页数：5

共 20 条

[1]

ALLEN GH, 1941, ORG SYN COLL, V1, P156

[2]

Brem G., 1985, ISR J CHEM, V26, P291

[3] Etherification of phenols catalysed by solid-liquid phase transfer catalyst PEG400 without solvent [J].