Synthesis of 3-substituted-4H-1,4-benzoxazines via palladium-catalysed coupling reactions

被引：32

作者：

Buon, C ^{[1
]}

Bouyssou, P ^{[1
]}

Coudert, G ^{[1
]}

机构：

[1] Univ Orleans, CNRS, Inst Chim Organ & Analyt, F-45067 Orleans 02, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 04期

关键词：

benzoxazines; coupling reactions; palladium and compounds; tin and compounds;

D O I：

10.1016/S0040-4039(98)02453-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Here is described a high yield synthesis of 3-substituted 4H-1,4-benzoxazines via palladium-catalysed coupling reactions between organostannanes and a vinylphosphate obtained from a benzoxazin-3-one derivative. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：701 / 702

页数：2

共 5 条

[1] BARBER C, 1991, SYNLETT, P197
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[3] Synthesis and further reactivity of functionalized lactam-derived enol triflates
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[4] Palladium-catalyzed functionalization of lactones via their cyclic ketene acetal phosphates. Efficient new synthetic technology for the construction of medium and large cyclic ethers
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (23) : 5467 - 5468
[5] A GENERAL AND CONVENIENT SYNTHESIS OF 2H-1,4-BENZOXAZIN-3(4H)-ONES
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JOGIBHUKTA, M
KRISHNAN, VSH
[J]. ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 1982, 14 (03) : 195 - 197

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