A zeolitic organo-metal lophosphate hybrid material with bimodal porosity

被引：85

作者：

Liao, YC ^{[1
]}

Liao, FL ^{[1
]}

Chang, WK ^{[1
]}

Wang, SL ^{[1
]}

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30043, Taiwan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 05期

关键词：

D O I：

10.1021/ja0390146

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first metal carboxylatophosphate, NTHU-2, contains inorganic ZnHPO4 layers linked by BDC units (BDC = 1,4-benzene dicarboxylate or terephthalic anion); the three-dimensional anionic framework has large pores with the smallest diameter being 1.36 nm; N2 sorption isotherms reveal both micro- and mesoporosity; the new material is photoluminescent and disassembles in water wherein the discharged organic fragments form mixed crystals. Copyright © 2004 American Chemical Society.

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页码：1320 / 1321

页数：2

相关论文

共 19 条

[1] A rational study of crystal engineering of supramolecular assemblies of 1,2,4,5-benzenetetracarboxylic acid [J].

Arora, KK ;

Pedireddi, VR .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (24) :9177-9185

[2] A MOLECULAR-SIEVE WITH 18-MEMBERED RINGS [J].

DAVIS, ME ;

SALDARRIAGA, C ;

MONTES, C ;

GARCES, J ;

CROWDER, C .

NATURE, 1988, 331 (6158) :698-699

[3] Ordered porous materials for emerging applications [J].

Davis, ME .

NATURE, 2002, 417 (6891) :813-821

[4]

GREGG SJ, 1981, ADSORPTION SURFACE A, pCH3

[5] Pore size determination in modified micro- and mesoporous materials.: Pitfalls and limitations in gas adsorption data analysis [J].

Groen, JC ;

Peffer, LAA ;

Pérez-Ramírez, J .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 60 (1-3) :1-17

[6]

Guillou N, 2001, ANGEW CHEM INT EDIT, V40, P2831, DOI 10.1002/1521-3773(20010803)40:15<2831::AID-ANIE2831>3.0.CO

[7]

2-Z

[8] Novel vanadium(V) compounds with a layer structure:: Synthesis, crystal structures, and solid state NMR spectroscopy of [(VO2)2(4,4′-bpy)0.5(4,4′-Hbpy)(XO4)]•H2O (X = P and As) [J].

Huang, LH ;

Kao, HM ;

Lii, KH .

INORGANIC CHEMISTRY, 2002, 41 (11) :2936-2940

[9] SYNTHESIS AND CHARACTERIZATION OF A NOVEL EXTRA LARGE RING OF ALUMINOPHOSPHATE JDF-20 [J].

HUO, QH ;

XU, RR ;

LI, SG ;

MA, ZG ;

THOMAS, JM ;

JONES, RH ;

CHIPPINDALE, AM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (12) :875-876

[10] Synthesis, crystal structure, magnetic susceptibility, and Mossbauer spectroscopy of a mixed-valence organic-inorganic hybrid compound:: (H3DETA)[Fe3(C2O4)2(HPO4)2(PO4)] (DETA = diethylenetriamine) [J].

Jiang, YC ;

Wang, SL ;

Lii, KH ;

Nguyen, N ;

Ducouret, A .

CHEMISTRY OF MATERIALS, 2003, 15 (08) :1633-1638