Methylzinc tert-butoxide tetrahydrofuran solvate

被引：10

作者：

Bond, AD ^{[1
]}

Linton, DJ ^{[1
]}

Wheatley, AEH ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801009667

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal structure of tetra-mu (3) -tert-butoxo-tetrakis(methylzinc) tetrahydrofuran (THF) solvate, [Zn-4(CH3)(4)(C4H9O)(4)].C4H8O, has been determined at 230 (1) K. The structure is based on a ((BuOZnMe)-Bu-t)(4) pseudo-cube and contains one lattice molecule of tetrahydrofuran per ((BuOZnMe)-Bu-t)(4) unit. Comparison with a previously reported unsolvated structure of methylzinc tert-butoxide suggests that this also contains lattice THF.

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页码：m298 / m300

页数：3

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