An insight into ion-transport by calixarenes;: the structure of the dipotassium complex of p-tert-butylcalix[8]arene crystallised from a protogenic, coordinating solvent [ethanol/diethylcarbonate (10:1)]

被引：22

作者：

Clague, NP

Clegg, W

Coles, SJ

Crane, JD

Moreton, DJ

Sinn, E

Teat, SJ

Young, NA

机构：

[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, Yorks, England

[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[3] CCLRC, Daresbury Lab, Warrington WA4 4AD, Cheshire, England

[4] BP Chem Additives Ltd, Hull Res Ctr, Hull HU12 8DS, N Humberside, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 04期

关键词：

D O I：

10.1039/a809401b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the dipotassium complex of the dianion of p-tert-butylcalix[8]arene crystallised from a protogenic, coordinating solvent (ethanol-diethylcarbonate, 10:1) shows that the metal ions are bound above and below the cavity of the calix[8]arene, which adopts a 'pinched' conformation.

引用

页码：379 / 380

页数：2

共 11 条

[1] COMPARISON OF THE X-RAY CRYSTAL-STRUCTURES OF THE SODIUM AND POTASSIUM 2,4,6-TRIS(TRIFLUOROMETHYL)PHENOXIDES (RO-) AND 2,4,6-TRIS(TRIFLUOROMETHYL)BENZENETHIOLATES (RS-) - [NA(OR)(THF)2]2, [K(OR)(THF)2(MU-THF)]2, [NA(SR)(THF)2.0.25THF]X AND [K(SR)(THF)]X (THF = TETRAHYDROFURAN)
BROOKER, S
EDELMANN, FT
KOTTKE, T
ROESKY, HW
SHELDRICK, GM
STALKE, D
WHITMIRE, KH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (03) : 144 - 146
[2] A new high-flux chemical and materials crystallography station at the SRS Daresbury .1. Design, construction and test results
Cernik, RJ
Clegg, W
Catlow, CRA
BushnellWye, G
Flaherty, JV
Greaves, GN
Burrows, I
Taylor, DJ
Teat, SJ
Hamichi, M
[J]. JOURNAL OF SYNCHROTRON RADIATION, 1997, 4 : 279 - 286
[3] A novel titanium-oxygen ladder structure supported by calix[4]arene ligands, characterised by synchrotron crystallography
Clegg, W
Elsegood, MRJ
Teat, SJ
Redshaw, C
Gibson, VC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (18): : 3037 - 3039
[4] Synthesis and X-ray structures of tetralithium derivatives of tert-butylcalix[4]arene containing unique Li-O cores based on a square-pyramidal geometry
Davidson, MG
Howard, JAK
Lamb, S
Lehmann, CW
[J]. CHEMICAL COMMUNICATIONS, 1997, (17) : 1607 - 1608
[5] The United Kingdom Chemical Database Service
Fletcher, DA
McMeeking, RF
Parkin, D
[J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1996, 36 (04): : 746 - 749
[6] CALIXARENES
GUTSCHE, CD
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1983, 16 (05) : 161 - 170
[7] CALIXARENE-CUPPED CESIUM - A COORDINATION CONUNDRUM
HARROWFIELD, JM
OGDEN, MI
RICHMOND, WR
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (17) : 1159 - 1161
[8] CATION-TRANSPORT FROM MULTIPLE ALKALI CATION MIXTURES USING A LIQUID MEMBRANE SYSTEM CONTAINING A SERIES OF CALIXARENE CARRIERS
IZATT, SR
HAWKINS, RT
CHRISTENSEN, JJ
IZATT, RM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (01) : 63 - 66
[9] Cooperative metal ion binding by metal-organized crown ether
Kobuke, Y
Kokubo, K
Munakata, M
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (51) : 12751 - 12758
[10] McKewey M. A., 1996, COMPREHENSIVE SUPRAM, V1, P537

← 1 2 →