New, practical and effective sources of fluoride ion for desilylation to form carbon anions

被引：31

作者：

Busch-Petersen, J ^{[1
]}

Bo, YX ^{[1
]}

Corey, EJ ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(99)00166-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Suspensions of powdered glassy solids prepared by fusion of 1 : 1 mixtures of CsF-CsOH and CsF-CsCl effectively catalyze the generation of enolates, acetylide and other anions from trimethylsilylated precursors. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2065 / 2068

页数：4

共 13 条

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