Porphyrin - Carbon nanotube composites formed by noncovalent polymer wrapping

被引:159
作者
Satake, A [1 ]
Miyajima, Y [1 ]
Kobuke, Y [1 ]
机构
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan
关键词
D O I
10.1021/cm048549a
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Stable porphyrin/single-walled nanotube (SWNT) composites were synthesized by condensation of tetraformylporphyrins and diaminopyrenes on SWNTs. The degree of interaction between SWNTs and porphyrin was evaluated by UV-vis and fluorescence spectra, and chemical removal of porphyrin from SWNTs. In the composites, the Soret and Q-bands of porphyrin moieties were significantly broadened and their fluorescence was almost quenched. Apparent extinction coefficients at the Soret bands of the composites were decreased to ca. 20%.
引用
收藏
页码:716 / 724
页数:9
相关论文
共 46 条
  • [1] Ago H, 1999, ADV MATER, V11, P1281, DOI 10.1002/(SICI)1521-4095(199910)11:15<1281::AID-ADMA1281>3.0.CO
  • [2] 2-6
  • [3] Photoconductivity study of modified carbon nanotube/oxotitanium phthalocyanine composites
    Cao, L
    Chen, HZ
    Wang, M
    Sun, JZ
    Zhang, XB
    Kong, FZ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (35) : 8971 - 8975
  • [4] Dissolution of full-length single-walled carbon nanotubes
    Chen, J
    Rao, AM
    Lyuksyutov, S
    Itkis, ME
    Hamon, MA
    Hu, H
    Cohn, RW
    Eklund, PC
    Colbert, DT
    Smalley, RE
    Haddon, RC
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (13): : 2525 - 2528
  • [5] Noncovalent engineering of carbon nanotube surfaces by rigid, functional conjugated polymers
    Chen, J
    Liu, HY
    Weimer, WA
    Halls, MD
    Waldeck, DH
    Walker, GC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (31) : 9034 - 9035
  • [6] Solution properties of single-walled carbon nanotubes
    Chen, J
    Hamon, MA
    Hu, H
    Chen, YS
    Rao, AM
    Eklund, PC
    Haddon, RC
    [J]. SCIENCE, 1998, 282 (5386) : 95 - 98
  • [7] Noncovalent sidewall functionalization of single-walled carbon nanotubes for protein immobilization
    Chen, RJ
    Zhang, YG
    Wang, DW
    Dai, HJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (16) : 3838 - 3839
  • [8] Curran SA, 1998, ADV MATER, V10, P1091, DOI 10.1002/(SICI)1521-4095(199810)10:14<1091::AID-ADMA1091>3.0.CO
  • [9] 2-L
  • [10] Selective interaction of a semiconjugated organic polymer with single-wall nanotubes
    Dalton, AB
    Stephan, C
    Coleman, JN
    McCarthy, B
    Ajayan, PM
    Lefrant, S
    Bernier, P
    Blau, WJ
    Byrne, HJ
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (43) : 10012 - 10016