Specific insertion reactions of a germylene, stannylene and plumbylene into the unique P-P bond of the hexaphospha-pentaprismane cage, P6C4tBu4:: Crystal and molecular structures of P6C4tBu4ER2 (E = Ge, Sn, R = N(SiMe3)2; E = Pb, R = (C6H3(NMe2)2-2,6)

被引：11

作者：

Al-Ktaifani, Mahmoud M. ^{[1
]}

Hitchcock, Peter B. ^{[1
]}

Lappert, Michael F. ^{[1
]}

Nixon, John F. ^{[1
]}

Uiterweerd, Philip ^{[1
]}

机构：

[1] Univ Sussex, Dept Chem, Sch Life Sci, Brighton BN1 9QJ, E Sussex, England

来源：

DALTON TRANSACTIONS | 2008年 / 21期

关键词：

D O I：

10.1039/b800458g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the cage compound (P6C4Bu4)-Bu-t with M{N(SiMe3)(2)}(2) (M = Ge or Sn) or Pb(C6H3(NMe2)(2-)2,6) at room temperature results in their specific insertion into the P-P bond connecting the two 5-membered (P3C2Bu2)-Bu-t rings. The products were fully characterised by multinuclear NMR spectroscopy and single crystal X-ray diffraction studies.

引用

页码：2825 / 2831

页数：7

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