Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

被引：1416

作者：

Cokoja, Mirza ^{[1
]}

Bruckmeier, Christian ^{[2
]}

Rieger, Bernhard ^{[2
]}

Herrmann, Wolfgang A. ^{[1
]}

Kuehn, Fritz E. ^{[1
]}

机构：

[1] Tech Univ Munich, Mol Catalysis Catalysis Res Ctr, Chair Inorgan Chem, D-85747 Garching, Germany

[2] Tech Univ Munich, Catalysis Res Ctr, WACKER Chair Macromol Chem, D-85747 Garching, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 37期

关键词：

carbon dioxide; homogeneous catalysis; organometalliccatalysts; renewable resources; sustainable chemistry; ASYMMETRIC ALTERNATING COPOLYMERIZATION; PHOTOCATALYTIC CO2 REDUCTION; HIGHLY EFFICIENT CATALYSTS; VISIBLE-LIGHT IRRADIATION; ALDIMINE ZINC-COMPLEXES; ACID-BASE-EQUILIBRIUM; SINGLE-SITE CATALYSTS; C-C-LINKAGE; CYCLIC CARBONATES; CYCLOHEXENE OXIDE;

D O I：

10.1002/anie.201102010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A plethora of methods have been developed over the years so that carbon dioxide can be used as a reactant in organic synthesis. Given the abundance of this compound, its utilization in synthetic chemistry, particularly on an industrial scale, is still at a rather low level. In the last 35 years, considerable research has been performed to find catalytic routes to transform CO 2 into carboxylic acids, esters, lactones, and polymers in an economic way. This Review presents an overview of the available homogeneous catalytic routes that use carbon dioxide as a C 1 carbon source for the synthesis of industrial products as well as fine chemicals. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：8510 / 8537

页数：28

共 342 条

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