Cyclometalated cis-chelated bidentate n-heterocyclic carbene palladium complexes: Synthetic, structural, and catalytic studies

被引：64

作者：

Liu, Zhen ^{[1
]}

Zhang, Tao ^{[2
]}

Shi, Min ^{[1
,2
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

[2] E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 11期

关键词：

D O I：

10.1021/om800069p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel cyclometalated cis-chelated bidentate N-heterocyclic carbene palladium complexes derived from binaphthyl-2,2'-diamine (BINAM) have been successfully synthesized, and the cyclometalated cis-chelated bidentate NHC-palladium(II) complex 5a has been characterized by X-ray crystal structure diffraction. Moreover, we found that these novel NHC-palladium(II) complexes are quite effective in Suzuki-Miyaura coupling reactions and Friedel-Crafts reactions under mild conditions.

引用

页码：2668 / 2671

页数：4

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