Crystallization of Prussian Blue analogs beneath Langmuir films

被引:39
作者
Torres, GR
Agricole, A
Delhaes, P
Mingotaud, C
机构
[1] Univ Toulouse 3, IMRCP, F-31062 Toulouse 04, France
[2] CNRS, Ctr Rech Paul Pascal, F-33600 Pessac, France
关键词
D O I
10.1021/cm025587q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A positively charged monolayer spread at the gas-water interface was used to induce the crystallization of Prussian Blue derivatives. The interfacial crystal nucleation and growth lead to nanocubes oriented parallel to the interface. Such processes appear at much lower concentrations of the precursor ions than in bulk. These experiments open new opportunities for selecting the crystalline phases of various molecular materials.
引用
收藏
页码:4012 / +
页数:4
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