Reactions of α-sulfone disulfides with sulfinate anions

被引：1

作者：

Andrews, Christopher G. ^{[1
]}

Langler, Richard F. ^{[1
]}

机构：

[1] Mt Allison Univ, Dept Chem, Sackville, NB E0A 3C0, Canada

来源：

JOURNAL OF SULFUR CHEMISTRY | 2009年 / 30卷 / 02期

关键词：

alpha-sulfone disulfides; SS bond rupture; mesylmethyl disulfide; dysoxysulfone; alpha-benzoate disulfide; DYSOXYLUM-RICHII; LENTINUS-EDODES; DYSOXYSULFONE; LENTHIONINE; PRECURSOR; CHLORIDES;

D O I：

10.1080/17415990902725717

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Degenerate substitution reactions (at carbon) between the appropriate sulfinic acid salts and tosylmethyl methyl or mesylmethyl methyl disulfides have formed symmetrical disulfone disulfides in moderate yields. These products form in a redox process involving sulfinate anions following partial skeletal disassembly arising from rupture of the SS bond. The reaction of mesylmethyl methyl disulfide and sodium methanesulfinate provides a natural product, dysoxysulfone, in low yield.

引用

页码：137 / 144

页数：8

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