An investigation into the electrodeposition of AuCu-matrix particulate composites. Part II: Baths not containing free cyanide

被引：13

作者：

Bozzini, B

Giovannelli, G

Cavallotti, PL

机构：

[1] Univ Lecce, Fac Ingn, Dipartimento Ingn Innovaz, INFM, I-73100 Lecce, Italy

[2] Politecn Milan, Dipartimento Chim Fis Applicata, I-20131 Milan, Italy

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 2000年 / 30卷 / 05期

关键词：

electrodeposition of composites; electrodeposition of alloys; Au-Cu; B4C;

D O I：

10.1023/A:1003912711191

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In this paper we report on the electrodeposition of AuCu/B4C composites from acid baths with gold cyanocomplexes and no free cyanide. The electrochemical behaviour of the bath and the metallographic and crystalline structures of the electrodeposited alloys were studied with and without addition of particles. Electrochemical instabilities were previously observed for free-cyanide baths and their bearing on the structure of both pure matrix and composite electrodeposits were elucidated. No instabilities were observed in the alloy deposition from the acid baths containing complexed cyanide: compositionally and structurally homogeneous microstructures were obtained both with and without particle embedding.

引用

页码：591 / 594

页数：4