Syntheses and magnetic properties of hexanuclear [Cp2Mn3(L1)4]2 and octanuclear [Mn8(L2)12(μ4-O)2] (L1=2-HNC5H5N, L2=2-NH-3-Br-5-MeC5H3N, Cp = C5H5)

被引：27

作者：

Alvareza, CS

Bond, AD

Cave, D

Mosquera, MEG

Harron, EA

Layfield, RA

McPartlin, M

Rawson, JM

Wood, PT

Wright, DS

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, Oviedo 33006, Spain

[3] Univ N London, Sch Chem, London N7 9DB, England

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 24期

关键词：

D O I：

10.1039/b209496g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of manganocene, Cp2Mn, with 2-aminopyridine (L1H) or 2-amino-3-bromo-5-methylpyridine (L2H) give the novel hexanuclear and octanuclear Mn(II) amido cage compounds [Cp2Mn3(L-1)(4)](2) (1) and [Mn-8(L-2)(12)(mu(4)-O)(2)] (2); magnetic measurements on which provide a rare insight into the magnetic properties of amido-bridged metal clusters.

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收藏

页码：2980 / 2981

页数：2

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