Study of polyamide 6/6 synthesis carried out by interfacial polymerization on carbon fibre

被引：16

作者：

Botelho, EC

Scherbakoff, N

Rezende, MC ^{[1
]}

机构：

[1] Ctr Tenico Aerosp, Inst Aeronaut & Espaco, IAE CTA, Div Mat, Sao Paulo, Brazil

[2] Rhodia Rech Lyon, F-69192 Lyon, France

[3] Ctr Tecn Aeroespacial Aeronaut & Espaco, IAE CTA, Div Mat, BR-12228904 Sao Paulo, Brazil

来源：

POLYMER INTERNATIONAL | 2002年 / 51卷 / 11期

关键词：

polyamide; 6/6; nylon; interfacial polycondensation; thermoplastic composites; fibre matrix interface;

D O I：

10.1002/pi.1064

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polyamide 6/6 synthesis via interfacial polycondensation of hexamethylenediamine and adipoyl chloride with simultaneous impregnation of carbon fibres was investigated. This experimental work was carried out to study the recovery of carbon fiber cables by polyamide 6/6 using six different concentrations of the monomer. Variation in the polyamide monomer concentration resulted in significant changes of chemical and morphological characteristics of the polyamide 6/6 and its composite with carbon fibre. Carbon fibre impregnation was evaluated by scanning electron microscopy (SEM), optical microscopy (OM) and thermogravimetric analysis (TGA), and the polyamide coating obtained in different concentrations was evaluated by differential scanning calorimetry (DSC), energy dispersive spectroscopy (EDS) analysis and TGA. (C) 2002 Society of Chemical Industry.

引用

页码：1261 / 1267

页数：7

共 34 条

[1] PREPARATION AND CHARACTERIZATION OF SELECTIVELY ISOTOPICALLY LABELED NYLON-66 POLYMERS [J].

ANGELO, RJ ;

MIURA, H ;

GARDNER, KH ;

CHASE, DB ;

ENGLISH, AD .

MACROMOLECULES, 1989, 22 (01) :117-121

[2]

*ASTM, 1982, 337975 ASTM D

[3]

Barber D, 2001, PLOUGHSHARES, V27, P9

[4]

BOTELHO E.C., 1999, POLIMEROS, V9, P59

[5]

BOTELHO EB, IN PRESS J ADV MAT

[6]

Botelho EC, 2001, CARBON, V39, P45

[7] Synthesis of polyamide 6/6 by interfacial polycondensation with the simultaneous impregnation of carbon fibers [J].

Botelho, EC ;

Scherbakoff, N ;

Rezende, MC ;

Kawamoto, AM ;

Sciamareli, J .

MACROMOLECULES, 2001, 34 (10) :3367-3375

[8]

BOTELHO EC, 2000, MAT RES, V3, P19

[9]

BOTELHO EC, 2000, 7 LAT S POL SYNTH PO, P242

[10]

BOTELHO EC, 2001, Patent No. 65617

← 1 2 3 4 →