Manipulation and characterization of xenon-metalloporphyrin complexation with a scanning tunneling microscope

被引：18

作者：

Qiu, XH

Nazin, GV

Hotzel, A

Ho, W ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Phys & Astron, Irvine, CA 92697 USA

[2] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 49期

关键词：

D O I：

10.1021/ja0272639

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of a series of Xe-CuEtiol [Cu(II) etioporphyrin I] complexes on Cu(001) surface was identified by scanning tunneling microscopy (STM) at cryogenic condition. The binding sites of xenon to CuEtiol molecule were directly revealed by high-resolution STM images in combination with controlled manipulation. The interaction between xenon atoms and CuEtiol in the on-top configuration is suggestive of a charge-induced dipole interaction. The structural parameters obtained with the STM complement results from spectroscopic studies of van der Waals complexes.

引用

页码：14804 / 14809

页数：6

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