Static light scattering from microgel particles:: Model of variable dielectric permittivity

被引:31
作者
Fernández-Nieves, A [1 ]
de las Nieves, FJ
Fernández-Barbero, A
机构
[1] Univ Almeria, Dept Appl Phys, Grp Complex Fluids Phys, Almeria 04120, Spain
[2] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
关键词
D O I
10.1063/1.1629281
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We perform static light scattering experiments on a dilute suspension of microgel particles and model the resultant form factors P(q) by assuming an exponentially decaying dielectric permittivity. The result is that P(q) is a Lorentzian function of the scattering wavevector q for length scales greater than the particle size; the width approximately corresponding to twice the particle radius. This simple model reasonably accounts for scattered light from both swollen and shrunken microgel phases. (C) 2004 American Institute of Physics.
引用
收藏
页码:374 / 378
页数:5
相关论文
共 20 条
[1]   Functional hydrogel structures for autonomous flow control inside microfluidic channels [J].
Beebe, DJ ;
Moore, JS ;
Bauer, JM ;
Yu, Q ;
Liu, RH ;
Devadoss, C ;
Jo, BH .
NATURE, 2000, 404 (6778) :588-+
[2]  
Dhont J. K., 1996, INTRO DYNAMICS COLLO
[3]  
Duracher D, 1999, J POLYM SCI POL CHEM, V37, P1823
[4]   Structural modifications in the swelling of inhomogeneous microgels by light and neutron scattering -: art. no. 051803 [J].
Fernández-Barbero, A ;
Fernández-Nieves, A ;
Grillo, I ;
López-Cabarcos, E .
PHYSICAL REVIEW E, 2002, 66 (05) :10-051803
[5]   Structure formation from mesoscopic soft particles -: art. no. 051603 [J].
Fernández-Nieves, A ;
van Duijneveldt, JS ;
Fernández-Barbero, A ;
Vincent, B ;
de las Nieves, FJ .
PHYSICAL REVIEW E, 2001, 64 (05) :10-051603
[6]   Charge controlled swelling of microgel particles [J].
Fernández-Nieves, A ;
Fernández-Barbero, A ;
Vincent, B ;
de las Nieves, FJ .
MACROMOLECULES, 2000, 33 (06) :2114-2118
[7]  
FERNANDEZNIEVES.A, UNPUB
[8]  
Flory P J., PRINCIPLES POLYM CHE
[9]  
Gan DJ, 2001, J AM CHEM SOC, V123, P7511, DOI 10.1021/ja010609f
[10]  
Guillermo A, 2000, J POLYM SCI POL PHYS, V38, P889, DOI 10.1002/(SICI)1099-0488(20000315)38:6<889::AID-POLB9>3.3.CO