Determination of triazine pesticides using a new enzyme inhibition tyrosinase OPEE operating in chloroform

被引:31
作者
Campanella, L [1 ]
Bonanni, A [1 ]
Martini, E [1 ]
Todini, N [1 ]
Tomassetti, M [1 ]
机构
[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy
关键词
triazine; pesticide analysis; tyrosinase biosensor; inhibition OPEE;
D O I
10.1016/j.snb.2005.03.082
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A biosensor method for the determination of triazine pesticides based on an inhibition organic phase enzyme electrode (OPEE) is described. The OPEE was developed using a tyrosinase biosensor assembled in the version operating in organic phase and used to determine triazine pesticides by exploiting their power to inhibit the tyrosinase enzyme. The results show the full validity of the method, which has also been optimized by comparing two different operating procedures. Lastly, the tyrosinase OPEE was also used to test triazine recovery from common vegetal samples, obtaining recoveries always >90%. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:505 / 514
页数:10
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